Фазовая диаграмма системы Nb-Te

К оглавлению: Другие диаграммы (Others phase diargams)


Nb-Te (Niobium-Tellurium) Editor The Nb-Te phase diagram was constructed by [89Cha] based on the reported intermediate phases and a partial phase diagram (70 to 85 at.% Te) given by [ 72Smi]. [88Mis], who reported a substantially different phase diagram, found the peritectic formation temperature of NbTe4 at 750 C, whereas [72Smi] observed it at 465 C. NbTe2 exists in three polymorphic forms, but there are no compounds between NbTe2 and NbTe4 in the diagram of [88Mis]. Apparently, [ 88Mis] was unaware of [72Smi], and [89Cha] was unaware of [88Mis]. Therefore, the disagreement has not been clarified.-H.O. 60Nov: A.V. Novoselova, L.A. Grigoryan, and Yu.P. Simanov, Dokl. Akad. Nauk SSSR, 135, 864-867 (1960) in Russian; TR: Proc. Acad. Sci. USSR, Chem. Sect., 135, 1375-1378 (1960). 63Sel: K. Selte and A. Kjekshus, Acta Chem. Scand., 17(9), 2560-2562 (1963). 64Sel1: K. Selte and A. Kjekshus, Acta Chem. Scand., 17, 1568-1572 (1964). 64Sel2: K. Selte and A. Kjekshus, Acta Crystallogr., 18(3), 690-696 (1964). 65Sel: K. Selte and A. Kjekshus, Acta Chem. Scand., 19(1), 258-260 (1965). 72Smi: D.L. Smith, A.R. Mochel, J.J. Banewicz, and J.A. Maguire, J. Less- Common Met., 26(1), 139-144 (1975). 88Mis: A.V. Mishchenko, I.V. Yushina, and V.E. Fedorov, Zh. Neorg. Khim., 33(2) , 437-442 (1988) in Russian; TR: Russ. J. Inorg. Chem., 33(2), 244-247 (1988). 89Cha: G. Chattopadhyay and S.R. Bharadwaj, Evaluated Phase Diagrams of Binary Metal-Tellurium Systems of the D-Block Transition Elements, Bhabha Atomic Research Centre, Bombay, 95-97 (1989). 1