Фазовая диаграмма системы In-Tm

К оглавлению: Другие диаграммы (Others phase diargams)


In-Tm (Indium-Thulium) H. Okamoto The assessed Tm-In phase diagram is based primarily on the work of [83Yat], with review of the experimental data of [74Die]. The accuracy of the temperature scale may be no better than с5 C, because all temperatures in [ 83Yat] are rounded to the nearest 10 C. The existence of a b = a allotropic transition in pure Tm has not been well established. Therefore, "(bTm)" may be an impurity-stabilized phase. Although it has never been identified positively, the existence of Tm3In5 is almost certain according to similarity in the Tm-In and Er-In phase diagrams [83Yat]. The solubility of Tm in liquid In was measured by [74Die] between 400 and 500 C; log C = 0.786 - 1160/T, where C is in at.% Tm and T is in K. According to this expression, the eutectic composition is 99.988 at.% In. Therefore, the assessed diagram shows that the solubility of Tm in (In) is negligible and the eutectic temperature is only slightly lower than the melting point of In. 64Kuz: Yu.B. Kuz'ma and V.Ya. Markiv, Kristallografiya, 9(2), 279-280 (1964) in Russian; TR: Sov. Phys. Crystallogr., 9(2), 218-220 (1964). 65Har: I.R. Harris and G.V. Raynor, J. Less-Common Met., 9, 7-19 (1965). 66Mor: J.L. Moriarty, J.E. Humphreys, R.O. Gordons, and N.C. Baenziger, Acta Crystallogr., 21, 840-841 (1966). 68Pal: A. Palenzona, J. Less-Common Met., 16, 379-384 (1968). 69Bus: K.H.J. Buschow, H.W. De Wijn, and A.M. Van Diepen, J. Chem. Phys., 50(1) , 137-141 (1969). 74Die: E.N. Dieva, Physicochemical Studies of Liquid Metals and Alloys, V.G. Bamburov, Ed., Izd. Ural'sk. Nauch. Tsentra Akad. Nauk SSSR, Sverdlovsk, 98- 104 (1974). 83Yat: S.P. Yatsenko, A.A. Semyannikov, H.O. Shakarov, and E.G. Fedorova, J. Less-Common Met., 90(1), 95-108 (1983). Submitted to the APD Program. Complete evaluation contains 1 figure, 3 tables, and 10 references. Special Points of the Tm-In System