Фазовая диаграмма системы Cd-Th

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Cd-Th (Cadmium-Thorium) J. Dutkiewicz The assessed phase diagram for the Cd-Th system is based on the work of [81Bat] and [81Pal], with review of the data of [60Joh]. The melting temperatures of the pure elements have been adjusted to agree with [Melt]. The equilibrium phases are (1) the liquid, L; (2) six intermetallic compounds- Cd11Th, Cd5Th, Cd23Th6, Cd3Th, Cd2Th, and CdTh; and (3) three terminal solid solutions-(bTh), (aTh), and (Cd). The assessed Cd-rich liquidus is based on [ 81Bat]. The stoichiometry of Cd23Th6 was taken from [81Pal] due to isomorphism with Mn23Th6 and the existence of Mg23Th6. The position of the eutectic at 0. 005 at.% Th is based on the liquidus data of [60Joh] and [81Bat]. The solubility of Th in (Cd) should be negligible because the lattice parameters of Cd do not change [81Pal] when alloyed with Th. The solid solubility of Cd in (Th) was not investigated. 60Joh: I. Johnson and K.D. Anderson, U.S. Atomic Energy Commission Rep. ANL- 6145, 70 (1960). 71For: M.L. Fornasini, J. Less-Common Met., 25, 329-332 (1971). 73Bru: G. Bruzzone, M.L. Fornasini, and F. Merlo, J. Less-Common Met., 30, 361- 375 (1973). 81Bat: J. Bates, M. Adler, J. Meisenhelder, W. Shinn, B.S. Tani, and M. Krumpelt, J. Less-Common Met., 77, 205-213 (1981). 81Pal: A. Palenzona and S. Cirafici, J. Less-Common Met., 77, 215-220 (1981). Submitted to the APD Program. Complete evaluation contains 2 figures, 3 tables, and 6 references. Special Points of the Cd-Th System