Фазовая диаграмма системы Au-Cd

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Au-Cd (Gold-Cadmium) H. Okamoto and T.B. Massalski The equilibrium phases of the Au-Cd system are (1) the liquid, L; (2) the fcc terminal solid solution, (Au), with a maximum solid solubility of 32.5 at.% Cd in (Au) at 627 C; (3) the phases a1 and a2 in the composition range between approximately 24 and 35 at.% Cd; (4) the CsCl-type b phase, with several forms of martensitic modifications at low temperatures; (5) a succession of related phases d, d›, and d›› at temperatures above approximately 305 C; (6) the unrelated Au3Cd5 phase below 340 C; (7) the e phase with a possible martensitic transformation at ~270 C; (8) the closely related h and h› phases; and (9) the cph terminal solid solution, (Cd), with a maximum solid solubility of 3.5 at.% Au in (Cd) at 309 C. The assessed phase diagram is based primarily on the work of [06Vog], [15Sal], [29Dur], [40Owe], [61Hir], [ 64Fil], [69Hir], and [73Kom]. The b› and b›› martensitic structures are observed primarily at about 47.5 and 50 at.% Cd, respectively. The d›› phase essentially corresponds to the g phase reported in [Hansen]. The phase fields of e and e› are tentative, because of the lack of experimental data. The h and h› phases are also tentative. 06Vog: R. Vogel, Z. Anorg. Allg. Chem., 48, 333-346 (1906) in German. 15Sal: P. Saldau, J. Inst. Met., 41, 175-176 (1929). 29Dur: P.J. Durrant, J. Inst. Met., 41, 139-171 (1929). 40Owe: E.A. Owen and E.A.O. Roberts, J. Inst. Met., 66, 389-400 (1940). 59Bir: H.K. Birnbaum, Trans. AIME, 215(10), 786-792 (1959). 61Hir: H. Hirabayashi and S. Ogawa, Acta Metall., 9(4), 264-274 (1961). 64Fil: J.D. Filby and J.N. Pratt, Trans. Faraday Soc., 60, 1934-1940 (1964). 69Hir: M. Hirabayashi, K. Hiraga, S. Yamaguchi, and N. Ino, J. Phys. Soc. Jpn., 27(1), 80-88 (1969). 73Kom: K.L. Komarek, E. Reiffenstein, and G. Stummerer, Monatsh. Chem., 104(6), 1570-1585 (1973) in German. Published in Phase Diagrams of Binary Gold Alloys, 1987, and Bull. Alloy Phase Diagrams, 7(1), Feb 1986. Complete evaluation contains 3 figures, 7 tables, and 109 references. Special Points of the Au-Cd System